Tropospheric ozone
Content
The reasons of ozone occurrence in the troposphere are:


 
The tropopause ”transmits” the ozone from the stratosphere to the troposphere.
Ultraviolet part of the light induces photochemical reactions of different substances, and forms ”photooxidants” that contains mainly ozone. Other components of the ”photooxidants” are hydrogen peroxide, hydroperoxide, peroxoacetyl nitrate and radicals. It means, destruction of the stratospheric ozone layer on one side and increase of the tropospheric ozone concentration on the other side are connected mutually together. As a consequence of ozone layer destruction it comes to the increased UV radiation resulting in more intensive photochemical reaction and consequently the increase of ozone concentration in troposphere.
Ozone formation is considerably enhanced by presence of hydrocarbons and oxides of nitrogen in the air. We can say ozone is formed only with the help of the solar radiation. The highest concentrations occur generally in the afternoon hours
Ozone relatively lightly reacts with other pollutants. For example, it oxidises NO to NO2. The result is the fact that the ozone concentration in the highly polluted region can be lowe then in the region polluted by Nox and VOC.